- 【Updated on May 12, 2025】 Integration of CiNii Dissertations and CiNii Books into CiNii Research
- Trial version of CiNii Research Knowledge Graph Search feature is available on CiNii Labs
- Suspension and deletion of data provided by Nikkei BP
- Regarding the recording of “Research Data” and “Evidence Data”
Geometrically Selective Synthesis of (<i>E</i>)-Enamides via Radical Allylation of Alkyl Halides with α-Aminoallylic Stannanes
-
- Kensuke Suzuki
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
-
- Yoshihiro Nishimoto
- Frontier Research Base for Young Researchers, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
-
- Makoto Yasuda
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
Search this article
Description
The reaction of α-(carbonylamino)allylic stannanes and alkyl halides using Et3B as a radical initiator selectively afforded (E)-enamides. A radical mechanism enables the E selectivity, which is unusual in a reaction using α-aminoallylic metals. In addition, this reaction system achieved a wide degree of functional group tolerance and an efficient chiral transfer reaction.
Journal
-
- Organic Letters
-
Organic Letters 21 (17), 6589-6592, 2019-07-05
American Chemical Society (ACS)
Related Data
See more- Tweet
Details 詳細情報について
-
- CRID
- 1360286992987255680
-
- ISSN
- 15237052
- 15237060
-
- Article Type
- journal article
-
- Data Source
-
- Crossref
- KAKEN
- OpenAIRE
