Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions
-
- Sobi Asako
- Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan
-
- Ikko Takahashi
- RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198 , Japan
-
- Takashi Kurogi
- Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan
-
- Yoshiaki Murakami
- KOBELCO ECO-Solutions Co., Ltd., 4-78-1 Wakinohama-cho, Chuo-ku, Kobe 651-0072 , Japan
-
- Laurean Ilies
- RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198 , Japan
-
- Kazuhiko Takai
- Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan
Description
<jats:title>Abstract</jats:title> <jats:p>An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.</jats:p>
Journal
-
- Chemistry Letters
-
Chemistry Letters 51 (1), 38-40, 2021-10-07
Oxford University Press (OUP)
- Tweet
Details 詳細情報について
-
- CRID
- 1360290548663518976
-
- NII Article ID
- 130008137567
-
- ISSN
- 13480715
- 03667022
-
- Data Source
-
- Crossref
- CiNii Articles
- KAKEN
