Catalytic C–H Arylation of Tetrathiafulvalenes for the Synthesis of Functional Materials

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  • Hideki Yorimitsu
    Department of Chemistry, Graduate School of Science
  • Aya Yoshimura
    Department of Applied Chemistry, Graduate School of Science and Engineering
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering

説明

<jats:title>Abstract</jats:title><jats:p>Sulfur-containing functional π-conjugated cores play key roles in materials science, mostly due to their unique electrochemical and photophysical properties. Among these, the excellent electron donor tetrathiafulvalene (TTF) has occupied a central position since the emergence of organic electronics. Peripheral C–H modification of this highly useful sulfur-containing motif has resulted in the efficient creation of new molecules that expand the applications of TTFs. This Short Review begins with the development of the palladium-catalyzed direct C–H arylation of TTF. Subsequently, it summarizes the applications of this efficient C–H transformation for the straightforward synthesis of useful TTF derivatives that are employed in a variety of research fields, demonstrating that the development of a new reaction can have a significant impact on chemical science.</jats:p><jats:p>1 Introduction</jats:p><jats:p>2 Development of the Palladium-Catalyzed Direct C–H Arylation of TTF</jats:p><jats:p>3 Synthesis of TTF-Based Tetrabenzoic Acid and Tetrapyridine for MOFs</jats:p><jats:p>4 Synthesis of TTF-Based Tetrabenzaldehyde and Tetraaniline for COFs</jats:p><jats:p>5 Tetraarylation of TTFAQ</jats:p><jats:p>6 Synthesis of Multistage-Redox TTF Derivatives</jats:p><jats:p>7 Miscellaneous Examples</jats:p><jats:p>8 Conclusions</jats:p>

収録刊行物

  • Synthesis

    Synthesis 52 (22), 3326-3336, 2020-09-08

    Georg Thieme Verlag KG

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