Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp<sup>2</sup>)–H Bond Functionalization

  • Shunsuke Kato
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan
  • Akira Onoda
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan
  • Alexander R. Grimm
    Institute of Biotechnology, RWTH Aachen University, Worringerweg 3, 52074 Aachen, Germany
  • Kengo Tachikawa
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan
  • Ulrich Schwaneberg
    Institute of Biotechnology, RWTH Aachen University, Worringerweg 3, 52074 Aachen, Germany
  • Takashi Hayashi
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan

書誌事項

公開日
2020-09-11
資源種別
journal article
権利情報
  • http://pubs.acs.org/page/policy/authorchoice_termsofuse.html
DOI
  • 10.1021/acs.inorgchem.0c02245
公開者
American Chemical Society (ACS)

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説明

A Cp*Rh(III)-dithiophosphate cofactor with “latent” catalytic activity was developed to construct an artificial metalloenzyme representing a new type of biohybrid catalyst which is capable of promo...

収録刊行物

  • Inorganic Chemistry

    Inorganic Chemistry 59 (19), 14457-14463, 2020-09-11

    American Chemical Society (ACS)

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