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Photoswitchable Nonlinear-Optical Crystal Based on a Dysprosium–Iron Nitrosyl Metal Assembly
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- Masaya Komine
- Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Kenta Imoto
- Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Asuka Namai
- Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Marie Yoshikiyo
- Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Shin-ichi Ohkoshi
- Department of Chemistry, School of Science, The University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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Description
Nitrosyl metal complexes (M-NO), in which nitrosyl ligands are coordinated to transition-metal ions, have been studied from the viewpoints of physiological activity, catalytic activity, and photosensitivity. The structural flexibility and electric polarization of the nitrosyl ligand are attractive characteristics. Herein we show a photoswitchable nonlinear-optical (NLO) crystal based on a dysprosium-iron nitrosyl assembly. This crystal is composed of a one-dimensional chain structure in the polar
Journal
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- Inorganic Chemistry
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Inorganic Chemistry 60 (4), 2097-2104, 2021-01-26
American Chemical Society (ACS)
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Keywords
- photoswitchable nonlinear-optical
- nitrosyl ligands
- polarization
- Chemical Sciences not elsewhere classified
- photoinduced linkage isomerization
- nitrosyl ligand
- 535
- metal nitrosyl sites
- switchable NLO crystal
- Photoswitchable Nonlinear-Optical C.
- Astronomical and Space Sciences not elsewhere classified
- SHG microscopy
- Pna 2 1 space group
- SHG signal reversibly changes
- Physical Sciences not elsewhere classified
- 804 nm laser lights
- chain structure
- Nitrosyl
- NLO effect
- transition-metal ions
- Cancer
Details 詳細情報について
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- CRID
- 1360291932842611072
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- ISSN
- 1520510X
- 00201669
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- PubMed
- 33497219
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE
