Influence of nanoscale Ag2Te precipitates on the thermoelectric properties of the Sn doped P-type AgSbTe2 compound
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- Rajeshkumar Mohanraman
- National Tsing Hua University 1 Department of Engineering and System Science, , Hsinchu, Taiwan
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- Raman Sankar
- National Taiwan University 4 Center for Condensed Matter Sciences, , Taipei, Taiwan
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- Fang-Cheng Chou
- National Taiwan University 4 Center for Condensed Matter Sciences, , Taipei, Taiwan
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- Chih-Hao Lee
- National Tsing Hua University 1 Department of Engineering and System Science, , Hsinchu, Taiwan
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- Yoshiyuki Iizuka
- Academia Sinica 5 Institute of Earth Sciences, , Taipei, Taiwan
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- I. Panneer Muthuselvam
- National Taiwan University 4 Center for Condensed Matter Sciences, , Taipei, Taiwan
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- Yang-Yuan Chen
- Academia Sinica 2 Institute of Physics, , Taipei, Taiwan
説明
<jats:p>We report a maximal figure of merit (ZT) value of 1.1 at 600 K was obtained for the sample of which x = 0.03, representing an enhancement greater than 20% compared with a pristine AgSbTe2 sample. This favorable thermoelectric performance originated from the optimal Sn2+ substitution for Sb3+ in AgSbTe2, which not only increased electrical conductivity but also led to a substantial reduction in thermal conductivity that was likely caused by an enhanced phonon-scattering mechanism through the combined effects of lattice defects and the presence of Ag2Te nanoprecipitates dispersed in the matrix.</jats:p>
収録刊行物
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- APL Materials
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APL Materials 2 (9), 096114-, 2014-09-01
AIP Publishing