Catalytic Asymmetric Ring-Opening of <i>meso-</i>Aziridines with Malonates under Heterodinuclear Rare Earth Metal Schiff Base Catalysis
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- Yingjie Xu
- Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Luqing Lin
- Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Motomu Kanai
- Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Shigeki Matsunaga
- Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
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- Masakatsu Shibasaki
- Institute of Microbial Chemistry, Tokyo, Kamiosaki 3-14-23, Shinagawa-ku, Tokyo 141-0021, Japan
書誌事項
- 公開日
- 2011-03-28
- DOI
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- 10.1021/ja201492x
- 10.1002/chin.201137026
- 公開者
- American Chemical Society (ACS)
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説明
<jats:title>Abstract</jats:title><jats:p>Fused as well as alkyl‐disubstituted aziridines undergo ring opening under catalysis of a complex derived from a 1:1:1 mixture of Broensted basic alkoxide La(OiPr)<jats:sub>3</jats:sub>, Lewis acidic triflate Yb(OTf)<jats:sub>3</jats:sub>, and axially chiral Schiff base BBN.</jats:p>
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 133 (15), 5791-5793, 2011-03-28
American Chemical Society (ACS)
