Controlled Adsorption Orientation for Double-Decker Complexes

  • Tomohide Takami
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Tao Ye
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Dennis P. Arnold
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Ken-ichi Sugiura
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Rongming Wang
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Jiangzhuang Jiang
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...
  • Paul S. Weiss
    Visionarts Research, Inc., 5-3-22-A301 Minami-Aoyama, Minato-ku, Tokyo 107-0062, Japan, Departments of Chemistry and Physics, The Pennsylvania State University, 104 Davey Laboratory, University Park, Pennsylvania 16802, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia, Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, Tokyo 192-0397, Japan, and Department of Chemistry, Shandong University, Jinan...

説明

Control of the molecular orientation of double-decker complexes comprised of rare-earth metals sandwiched with naphthalocyanine and porphyrin/phthalocyanine, at the interface of a graphite surface and 1-phenyloctane solution, has been demonstrated for the future application of molecular rotor assembly. Scanning tunneling microscope images clarified the internal structures of the top ligands. The observed images indicate that naphthalocyanine ligands were selectively adsorbed onto the graphite surface and the counterpart ligands of porphyrin/phthalocyanine were oriented off the surface. Control of the orientation of monolayers of mixed double-decker complexes has also been demonstrated.

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