Globe‐trotting Hydrogens on the Surface of the Fullerene Compound C<sub>60</sub>H<sub>6</sub>(N(CH<sub>2</sub>CH<sub>2</sub>)<sub>2</sub>O)<sub>6</sub>
書誌事項
- 公開日
- 1991-10
- 権利情報
-
- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
-
- 10.1002/anie.199113091
- 公開者
- Wiley
この論文をさがす
説明
<jats:p><jats:bold>The [1,5] sigmatropic migration of hydrogen in the adduct between buckminsterfullerene</jats:bold> C<jats:sub>60</jats:sub> and morpholine (Hmorph) is fast at −25°C already. Elemental analysis, thermogravimetry, IR and NMR spectroscopy, and cyclic voltammetry all support the formulation of the adduct as C<jats:sub>60</jats:sub>H<jats:sub>6</jats:sub> (morph)<jats:sub>6</jats:sub>. The amine is covalently added to six pyracylene units. The small activation barrier to the migration is astounding, especially as large changes in the C<jats:sub>60</jats:sub> framework are involved.</jats:p>
収録刊行物
-
- Angewandte Chemie International Edition in English
-
Angewandte Chemie International Edition in English 30 (10), 1309-1310, 1991-10
Wiley