Note on the Theory of Diffusion Controlled Reactions : Application to Photodissociation in Solution
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- Louis Monchick
- Department of Chemistry, University of Notre Dame, Notre Dame, Indiana
書誌事項
- 公開日
- 1956-02-01
- DOI
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- 10.1063/1.1742482
- 公開者
- AIP Publishing
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説明
<jats:p>The theory of diffusion controlled reactions has been reconsidered in the light of modern transport theory, and it has been concluded that the use of the Smoluchowski equation is valid for most problems of usual interest. The probability of reaction has been calculated for two molecules initially separated by a distance r′, in the presence of a third reactant present in uniform concentration. The resulting formulas have been used to discuss the quantum yields of photodissociation of Br2, Br3—, and I3— in aqueous solution. The dependence on temperature and wavelength can be qualitatively accounted for.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 24 (2), 381-385, 1956-02-01
AIP Publishing