Synthesis of the E Ring Segment of Ciguatoxin CTX3C via the Negishi Coupling of Cyclic Ketene Acetal Triflate

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<jats:title>Abstract</jats:title><jats:p>The stereocontrolled synthesis of the E‐ring segment of the title toxin (IX) is achieved via key C‐C bond formation by Negishi coupling of cyclic ketene acetal triflate (III) with zinc homoenolate (IV).</jats:p>

Journal

  • HETEROCYCLES

    HETEROCYCLES 86 (2), 997-, 2012

    CLOCKSS Archive

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