Direct Photoexcitation of Borate Enabling Minisci Reaction

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  • Marin Kemmochi
    Division of Pharmaceutical Science Graduate School of Medical Sciences Kanazawa University Kakuma-machi Kanazawa 920-1192 Japan
  • Yusuke Miyamoto
    Division of Pharmaceutical Science Graduate School of Medical Sciences Kanazawa University Kakuma-machi Kanazawa 920-1192 Japan
  • Yuto Sumida
    Division of Pharmaceutical Science Graduate School of Medical Sciences Kanazawa University Kakuma-machi Kanazawa 920-1192 Japan
  • Hirohisa Ohmiya
    Division of Pharmaceutical Science Graduate School of Medical Sciences Kanazawa University Kakuma-machi Kanazawa 920-1192 Japan

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<jats:title>Abstract</jats:title><jats:p>The photoexcitable borate enabling Minisci C−H alkylation of heteroarene has been described. This protocol using alkylborate only needed O<jats:sub>2</jats:sub> and visible light, which provides a considerably clean system. The direct photoexcitation of alkylborate allowed the generation of <jats:italic>tertiary</jats:italic>, <jats:italic>secondary</jats:italic>, and <jats:italic>primary</jats:italic>‐alkyl radical including methyl radical. This light‐driven Minisci reaction gave a choice for the functionalization of heteroarenes.</jats:p>

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