A New Protocol for Catalytic Reduction of Alkyl Chlorides Using an Iridium/Bis(benzimidazol-2′-yl)pyridine Catalyst and Triethylsilane

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  • Takahide Fukuyama
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University
  • Ilhyong Ryu
    Organization for Research Promotion, Osaka Prefecture University
  • Yuki Hamada
    Department of Chemistry, Graduate School of Science, OsakaPrefecture University

Abstract

<jats:title>Abstract</jats:title><jats:p>The reduction of alkyl chlorides using triethylsilane is investigated. Primary, secondary, tertiary, and benzylic C–Cl bonds are effectively converted into C–H bonds using an [IrCl(cod)]2/2,6-bis(benzimidazol-2′-yl)pyridine catalyst system. This catalyst system is quite simple since the tridentate N-ligand can be easily prepared in one step from commercially available reagents.</jats:p>

Journal

  • Synthesis

    Synthesis 53 (18), 3404-3408, 2021-06-11

    Georg Thieme Verlag KG

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