Sub‐Nanometer‐Sized Iridium Species Decorated on Mesoporous Co<sub>3</sub>O<sub>4</sub> for Electrocatalytic Oxygen Evolution

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  • Wenquan Wang
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Shunming Xi
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Yalong Shao
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Xi Gao
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Jing Lin
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Chao Meng
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Wenjing Wang
    Yantai Engineering & Technology College No.92 Zhujiang Road Yantai, Shandong 264006 People's Republic of China
  • Xiaosong Guo
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.
  • Guicun Li
    College of Materials Science and Engineering Qingdao University of Science and Technology No.53 Zhengzhou Road, Qingdao Shandong 266042 People's Republic of China.

抄録

<jats:title>Abstract</jats:title><jats:p>Optimizing the surface structure at the atomic scale is crucial for developing effective catalysts. In this work, a hybrid material consisting of well‐dispersed sub‐nanometer‐sized (SNS) iridium (Ir) species decorated on mesoporous Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub> was fabricated as electrocatalyst for the oxygen evolution reaction (OER) through pyrolysis of IrCl<jats:sub>3</jats:sub>/Co(NO<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub> complexes confined within the mesoporous KIT‐6 template. It was found that the KIT‐6 template played a critical role in the formation of SNS Ir species. The optimized Ir−Co<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>‐1 showed highly efficient OER catalytic performance with an overpotential of 1.527 V to achieve the current density of 10 mA cm<jats:sup>−2</jats:sup>, and superior stability in alkaline condition. The electrochemical results demonstrated that moderate Ir incorporation was conductive to form the high valence Co ions in form of Co oxyhydroxide during the OER process. The present work would open a new route for material design of SNS Ir species decorated mesoporous metal oxides for the application in catalysis.</jats:p>

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