Strategies for Improving the Functionality of Zeolitic Imidazolate Frameworks: Tailoring Nanoarchitectures for Functional Applications

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  • Yusuf Valentino Kaneti
    International Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS) 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan
  • Saikat Dutta
    Department of Chemical Engineering National Taiwan University Taipei 10617 Taiwan
  • Md. S. A. Hossain
    Australian Institute for Innovative Materials (AIIM) University of Wollongong Squires Way North Wollongong NSW 2500 Australia
  • Muhammad J. A. Shiddiky
    School of Natural Sciences Queensland Micro and Nanotechnology Centre Griffith University Nathan Campus QLD 4111 Australia
  • Kuo‐Lun Tung
    Department of Chemical Engineering National Taiwan University Taipei 10617 Taiwan
  • Fa‐Kuen Shieh
    Department of Chemistry National Central University Chung‐Li 32001 Taiwan
  • Chia‐Kuang Tsung
    Department of Chemistry Merkert Chemistry Center Boston College Chestnut Hill Massachusetts 02467 USA
  • Kevin C.‐W. Wu
    Department of Chemical Engineering National Taiwan University Taipei 10617 Taiwan
  • Yusuke Yamauchi
    International Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS) 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan

書誌事項

公開日
2017-08-18
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#am
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201700213
公開者
Wiley

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説明

<jats:p>Zeolitic imidazolate frameworks (ZIFs), a subclass of metal–organic frameworks (MOFs) built with tetrahedral metal ions and imidazolates, offer permanent porosity and high thermal and chemical stabilities. While ZIFs possess some attractive physical and chemical properties, it remains important to enhance their functionality for practical application. Here, an overview of the extensive strategies which have been developed to improve the functionality of ZIFs is provided, including linker modifications, functional hybridization of ZIFs via the encapsulation of guest species (such as metal and metal oxide nanoparticles and biomolecules) into ZIFs, and hybridization with polymeric matrices to form mixed matrix membranes for industrial gas and liquid separations. Furthermore, the developed strategies for achieving size and shape control of ZIF nanocrystals are considered, which are important for optimizing the textural characteristics as well as the functional performance of ZIFs and their derived materials/hybrids. Moreover, the recent trends of using ZIFs as templates for the derivation of nanoporous hybrid materials, including carbon/metal, carbon/oxide, carbon/sulfide, and carbon/phosphide hybrids, are discussed. Finally, some perspectives on the potential future research directions and applications for ZIFs and ZIF‐derived materials are offered.</jats:p>

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