The Metal–Support Interaction Concerning the Particle Size Effect of Pd/Al<sub>2</sub>O<sub>3</sub> on Methane Combustion

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  • Kazumasa Murata
    Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan
  • Yuji Mahara
    Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan
  • Junya Ohyama
    Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan
  • Yuta Yamamoto
    Institute of Materials and Systems for Sustainability Nagoya University Nagoya Japan
  • Shigeo Arai
    Institute of Materials and Systems for Sustainability Nagoya University Nagoya Japan
  • Atsushi Satsuma
    Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan

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<jats:title>Abstract</jats:title><jats:p>The particle size effect of Pd nanoparticles supported on alumina with various crystalline phases on methane combustion was investigated. Pd/θ, α‐Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> with weak metal‐support interaction showed a volcano‐shaped dependence of the catalytic activity on the size of Pd particles, and the catalytic activity of the strongly interacted Pd/γ‐Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> increased with the particle size. Based on a structural analysis of Pd nanoparticles using CO adsorption IR spectroscopy and spherical aberration‐corrected scanning/transmission electron microscopy, the dependence of catalytic activity on Pd particle size and the alumina crystalline phase was due to the fraction of step sites on Pd particle surface. The difference in fraction of the step site is derived from the particle shape, which varies not only with Pd particle size but also with the strength of metal–support interaction. Therefore, this interaction perturbs the particle size effect of Pd/Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> for methane combustion.</jats:p>

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