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- Jun-ichiro Setsune
- Department of Chemistry, Graduate School of Science, Kobe University, Nada-ku, Kobe 657-8501, Japan
書誌事項
- 公開日
- 2016-11-01
- 資源種別
- journal article
- DOI
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- 10.1021/acs.chemrev.6b00430
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
A large number of porphyrinoids containing 2,2'-bipyrrole subunits have appeared since they were originally found as a component of sapphyrin and corrole, and it was found that the bipyrrole subunit endowed macrocycles with specific geometric features and electronic properties. Synthetic methods for bipyrrole-containing precursors for porphyrinoid are summarized in this review; these include coupling reactions of pyrrole rings, pyrrole ring-forming reactions leading directly to bipyrrole units, and synthetic reactions for oligopyrrolic compounds. Some hybrid oligopyrroles having nonpyrrole (hetero)aromatic ring(s) are also included. This review also describes porphyrinoids composed of bipyrrole subunits. Interesting electronic properties derived from strong cyclo-π-conjugation are highlighted in the bipyrrole-based porphyrinoids with or without meso-like carbons. Anion-binding chemistry is one of the main topics for bipyrrole-based macrocycles with less efficient or deficient cyclo-π-conjugation, such as those linked with electronically localized aromatic ring(s), with sp
収録刊行物
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- Chemical Reviews
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Chemical Reviews 117 (4), 3044-3101, 2016-11-01
American Chemical Society (ACS)
