Nickel(0)-Catalyzed [2 + 2 + 1] Carbonylative Cycloaddition of Imines and Alkynes or Norbornene Leading to γ-Lactams

  • Yoichi Hoshimoto
    Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
  • Tomoya Ohata
    Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
  • Yukari Sasaoka
    Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
  • Masato Ohashi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
  • Sensuke Ogoshi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

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<jats:title>Abstract</jats:title><jats:p>A key feature of the process is the use of phenyl formate as a CO source that enables carbonylation and prevents quenching of the catalyst.</jats:p>

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