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Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes
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- Takahiro Nishimura
- Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
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- Yuko Maeda
- Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
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- Tamio Hayashi
- Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
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Description
<jats:title>Abstract</jats:title><jats:p>The reaction is carried out with nitrogen‐bridged 1,6‐enynes to afford the chiral 3‐azabicyclo[4.1.0]heptenes with high enantioselectivities.</jats:p>
Journal
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- Organic Letters
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Organic Letters 13 (14), 3674-3677, 2011-06-21
American Chemical Society (ACS)
