Spin crossover, structural change, and metallization in NiAs-type FeO at high pressure

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公開日
2011-10-14
資源種別
journal article
権利情報
  • http://link.aps.org/licenses/aps-default-license
DOI
  • 10.1103/physrevb.84.134417
公開者
American Physical Society (APS)

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説明

We report high-spin to low-spin crossover of iron in NiAs (B8)-type Fe${}_{0.96}$O (FeO hereafter) at high pressure by a combination of in-situ x-ray emission spectroscopy (XES) and x-ray diffraction (XRD) measurements. The XES spectra show a loss of spin in B8-type FeO approximately above 119 GPa at 300 K, consistent with the \ensuremath{\sim}2.5% volume reduction around 120 GPa. The high-temperature XRD study also demonstrates a similar volume decrease at 1560--1780 K under the same pressure condition. While the crystal structure of FeO remains to be B8 type across such volume reduction, the atomic arrangements of Fe and O change from inverse to normal NiAs form with considerable decrease in $c$/$a$ axial ratio. With recent electrical resistance measurements, these suggest that iron spin crossover, inverse-normal structural change, and insulator-metal transition occur concurrently in B8 FeO around 120 GPa.

収録刊行物

  • Physical Review B

    Physical Review B 84 (13), 134417-, 2011-10-14

    American Physical Society (APS)

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