Transfer-hydrogenation and Transfer-hydrogenolysis. I. Transfer-hydrogenation of Cyclooctadienes Catalyzed by Dichlorobis(triphenylphosphine)iron(II)

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  • Takeshi Nishiguchi
    Department of Applied Chemistry, Faculty of Engineering, Nagoya University
  • Kazuo Fukuzumi
    Department of Applied Chemistry, Faculty of Engineering, Nagoya University

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<jats:title>Abstract</jats:title> <jats:p>Hydrogen transfer from a number of organic compounds to olefins in a homogeneous system was studied. In the case of hydrogen transfer to 1,5-cyclooctadiene, using dichlorobis(triphenylphosphine)iron(II) as the catalyst, dihydroxybenzenes, such as pyrocatechol and hydroquinone, were much superior to prim- and sec-alcohols, 1-dodecanethiol, and cyclohexene as hydrogen donors.</jats:p>

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