Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides
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- Hiromu Sugeta
- Institute for Protein Research, Osaka University
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- Akikatsu Go
- Institute for Protein Research, Osaka University
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- Tatsuo Miyazawa
- Institute for Protein Research, Osaka University
書誌事項
- 公開日
- 1973-11-01
- 権利情報
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/bcsj.46.3407
- 10.1002/chin.197408056
- 公開者
- Oxford University Press (OUP)
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説明
<jats:title>Abstract</jats:title> <jats:p>The infrared and Raman spectra of several dialkyl disulfides were measured and their conformations were discussed in relation with the characteristic S–S and C–S stretching vibrations. The infrared spectra in the solid state and the temperature dependence of Raman spectra were measured for ethyl methyl disulfide and diethyl disulfide. For ethyl methyl disulfide, the gauche-gauche isomer was more stable than the trans-gauche isomer by about 0.9 kcal/mol while for diethyl disulfide the gauche-gauche-gauche isomer was more stable than the trans-gauche-gauche isomer by about 0.6 kcal/mol in the liquid state. Only the gauche-gauche form for ethyl methyl disulfide and only the gauche-gauche-gauche form for diethyl disulfide were observed in the solid state.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 46 (11), 3407-3411, 1973-11-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360565169053370752
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- NII論文ID
- 130001974640
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- ISSN
- 13480634
- 21992924
- 00092673
- 00092975
- http://id.crossref.org/issn/00092673
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