Ferromagnetic Assemblies Composed of MnIII Salen-Type Complexes and a Tripodal FeIII Complex with an Imidazolate Bridge
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- Ryuta Ishikawa
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Hitoshi Miyasaka
- Department of Chemistry, Graduate School of Science, Tohoku University
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- Masahiro Yamashita
- Department of Chemistry, Graduate School of Science, Tohoku University
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<jats:title>Abstract</jats:title> <jats:p>The use of a low-spin FeIII complex bearing three imidazolate groups in a reaction with MnIII salen-type complexes provided two different imidazolate-bridged MnIII–FeIII assemblies, a dinuclear complex and a one-dimensional chain, dependent on the salen ligand and counter ion used. Both compounds exhibit a ferromagnetic exchange between MnIII and FeIII centers via the imidazolate linkage.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 82 (7), 816-818, 2009-07
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360565169058748416
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- NII論文ID
- 130004152618
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- ISSN
- 13480634
- 00092673
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