REACTION AND ACTIVATION VOLUMES FOR THE 1,4-CYCLOADDITION OF TETRACYANOETHYLENE TO α-METHYLSTYRENE IN 1,2-DICHLOROETHANE AT 25°C

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  • Yasuhiro Uosaki
    Department of Chemistry, Faculty of Science, Kyoto University
  • Masaru Nakahara
    Department of Chemistry, Faculty of Science, Kyoto University
  • Muneo Sasaki
    Department of Chemistry, Faculty of Science, Kyoto University
  • Jiro Osugi
    Department of Chemistry, Faculty of Science, Kyoto University

Abstract

<jats:title>Abstract</jats:title> <jats:p>The charge–transfer spectrum of tetracyanoethylene with α-methylstyrene in 1,2-dichloroethane at 25°C has been measured at high pressures up to 1500 bar. Volume changes associated with the charge–transfer complex formation and the 1,4-cycloaddition at 1 bar are −6.9±0.6 and −29.2±0.7 cm3 mol−1, respectively.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 8 (6), 727-730, 1979-06

    Oxford University Press (OUP)

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