Preparation, Crystal Structure and Electrical Properties of 2-Cyclopentanylidene-1,3-dithiolo[4,5-<i>d</i>]tetrathiafulvalene Derivatives

Yohji Misaki, Kazuya Kawakami, Hiroyuki Nishikawa, Hideki Fujiwara, Tokio Yamabe, Motoo Shiro

doi:10.1002/chin.199408180

Preparation, Crystal Structure and Electrical Properties of 2-Cyclopentanylidene-1,3-dithiolo[4,5-<i>d</i>]tetrathiafulvalene Derivatives

Yohji Misaki

Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Kyoto University
Kazuya Kawakami

Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Kyoto University
Hiroyuki Nishikawa

Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Kyoto University
Hideki Fujiwara

Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Kyoto University
Tokio Yamabe

Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Kyoto University
Motoo Shiro

Rigaku Corporation

説明

<jats:title>Abstract</jats:title> <jats:p>The title compounds (1) were prepared as the donor components for organic conductors. The molecular and crystal structures of bis(methylthio) derivative were determined by X-ray diffractional analysis. Among charge-transfer complexes and cation radical salts of 1 prepared so far, I3− salt of unsubstituted-1 and IBr2− salt of methylenedithio-1 showed metallic temperature dependence of conductivities.</jats:p>