Preparation of (+)-Tricyclo[6.2.1.02,7]undec-2(7)-en-3-one and Its Conversion into (+)-<i>epi</i>-<i>β</i>-Santalene

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<jats:title>Abstract</jats:title> <jats:p>Optically pure (+)-tricyclo[6.2.1.02,7]undec-2(7)-en-3-one was first prepared from (+)-tricyclo[6.2.1.02,7]undeca-4,9-dien-3-one in four steps. Conjugated addition occurred selectively from the methano-bridge side to give the 1,4-adduct which was converted into natural (+)-epi-β-santalene.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 24 (2), 95-96, 1995-02-01

    Oxford University Press (OUP)

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