Electrochemical Studies for Interaction between [Cu(salen)] and La(III) Ion in <i>N,N</i>-Dimethylformamide
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- Kazuhiro Manseki
- Department of Human Sensing and Functional Sensor Engineering, Graduate School of Science and Engineering, Yamagata University
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- Yuko Shimizu
- Department of Human Sensing and Functional Sensor Engineering, Graduate School of Science and Engineering, Yamagata University
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- Akiko Obata
- Department of Material and Biological Chemistry, Faculty of Science, Yamagata University
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- Hiroshi Sakiyama
- Department of Human Sensing and Functional Sensor Engineering, Graduate School of Science and Engineering, Yamagata University
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- Kei Unoura
- Department of Material and Biological Chemistry, Faculty of Science, Yamagata University
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- Masatomi Sakamoto
- Department of Human Sensing and Functional Sensor Engineering, Graduate School of Science and Engineering, Yamagata University
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- Yuzo Nishida
- Department of Material and Biological Chemistry, Faculty of Science, Yamagata University
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- Yoshihiko Sadaoka
- Department of Materials Science and Engineering, Faculty of Engineering, Ehime University
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- Hisashi Okawa
- Department of Chemistry, Faculty of Science, Kyushu University
説明
<jats:title>Abstract</jats:title> <jats:p>The interaction between [Cu(salen)] and La(III) in DMF was studied by cyclic voltammetry and EQCM (Electrochemical Quartz Crystal Microbalance) technique. The quasi-reversible redox wave of [Cu(salen)] around −1.1 V vs Ag/AgCl was replaced by a reduction wave around −0.9 V on forming a [Cu(salen)···La] complex. The CuLa complex disproportionated on the electrode to exhibit an anodic stripping of Cu(0) to Cu(II) around +0.2 V.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 30 (12), 1256-1257, 2001-12-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360565169063367296
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- NII論文ID
- 130004422029
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- ISSN
- 13480715
- 03667022
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- データソース種別
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