Selective One-pot Synthesis of Facial Tris-ortho-metalated Iridium(III) Complexes Using Microwave Irradiation

DOI PDF 被引用文献5件 参考文献13件
  • Hideo Konno
    National Institute of Advanced Industrial Science and Technology (AIST)16-1 Onogawa, Tsukuba, Ibaraki
  • Yoshiyuki Sasaki
    National Institute of Advanced Industrial Science and Technology (AIST)16-1 Onogawa, Tsukuba, Ibaraki

抄録

<jats:title>Abstract</jats:title> <jats:p>We report on a novel synthesis method for the production of two facial tris-ortho-metalated iridium(III) complexes, fac-[Ir(ppy)3] (1a; ppyH = 2-phenylpyridine) and fac-[Ir(tpy)3] (1b; tpyH = 2-(p-tolyl)pyridine), by the reaction of IrCl3·3H2O with a large excess of the corresponding 2-arylpyridine under microwave irradiation. The method does not require a dehalogenating reagent such as AgCF3SO3, and facial tris-ortho-metalated iridium(III) complexes can be obtained rapidly, selectively and efficiently.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 32 (3), 252-253, 2003-02-12

    Oxford University Press (OUP)

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