Synthesis of β-Amino Ketones by Iridium(III)-catalyzed Direct-Mannich Reaction
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- Shunsuke Sueki
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
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- Takeyuki Igarashi
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
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- Takayuki Nakajima
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
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- Isao Shimizu
- Department of Applied Chemistry, School of Science and Engineering, Waseda University
抄録
<jats:title>Abstract</jats:title> <jats:p>The direct-Mannich reaction of ketones 1, aldehydes 2, and anilines 3 was studied using catalytic amount of transition-metal complexes. The trivalent iridium complex, [IrCl2(H)(cod)]2, catalyzed the direct-Mannich reaction effectively to give various β-amino kenotes in good yields under mild conditions.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 35 (6), 682-683, 2006-06-01
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360565169064278400
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- NII論文ID
- 130004424302
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- ISSN
- 13480715
- 03667022
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- データソース種別
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