The Tishchenko Reaction: A Classic and Practical Tool for Ester Synthesis

DOI DOI PDF 11 Citations 45 References
  • Tsunetake Seki
    Department of Chemisrty, Graduate School of Arts and Sciences, The University of Tokyo
  • Tetsuo Nakajo
    Showa Denko K. K
  • Makoto Onaka
    Department of Chemisrty, Graduate School of Arts and Sciences, The University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>This article reviews the Tishchenko reaction: 2 RCHO → RCOOCH2R (R = hydrogen, alkyl, and aryl), describing the reaction mechanisms, homogeneous and heterogeneous catalysts developed for the reaction, a number of specific examples, and the utility of the reaction in the industrially large-scale production of ethyl acetate from acetaldehyde.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 35 (8), 824-829, 2006-06-27

    Oxford University Press (OUP)

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