Synthesis and Properties of New Tetrathiapentalene Donors Composed of Vinylogous TTFs

DOI HANDLE PDF 研究データあり 被引用文献4件 参考文献13件
  • Shintaro Iwamoto
    Department of Applied Chemistry, Graduate School of Engineering, Ehime University
  • Shunsuke Watanabe
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, and JST-CREST
  • Hiroyuki Fueno
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, and JST-CREST
  • Kazuyoshi Tanaka
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, and JST-CREST
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Engineering, Ehime University
  • 30212179
  • 90155119

説明

<jats:title>Abstract</jats:title> <jats:p>A bis-fused donor composed of TTF vinylogues, 2,5-bis(2-ethanediylidene-1,3-dithiole)-1,3,4,6-tetrathiapentalene (BisEDT, 1a) and its derivatives have been synthesized. Cyclic voltammograms of 1 consist of four-pairs of one-electron redox waves. X-ray structure analysis of tetrakis(methylthio)-1 (1b) reveals the donor adopts almost planar structure. The TCNQF4 complexes of 1 showed moderate conductivity of σrt=10−2 S cm−1 on a compressed pellet.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 37 (1), 82-83, 2007-12-15

    Oxford University Press (OUP)

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