Electron Mobility in a Mercury-mediated Duplex of Triazole-linked DNA (TLDNA)

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  • Hiroyuki Isobe
    Department of Chemistry, Tohoku University
  • Naomi Yamazaki
    Department of Chemistry, Tohoku University
  • Atsushi Asano
    PRESTO and Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Tomoko Fujino
    Department of Chemistry, Tohoku University
  • Waka Nakanishi
    Department of Chemistry, Tohoku University
  • Shu Seki
    PRESTO and Department of Applied Chemistry, Graduate School of Engineering, Osaka University

Abstract

<jats:title>Abstract</jats:title> <jats:p>A metal-ion-mediated duplex of triazole-linked DNA (TLDNA) was synthesized via thymine–mercury(II)–thymine (T–Hg–T) base pairing. The electron-transport properties of the mercury-mediated duplex deposited on a solid substrate were determined by time-resolved microwave conductivity (TRMC) measurements.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 40 (3), 318-319, 2011-02-19

    Oxford University Press (OUP)

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