Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage

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  • Yuto Hashimoto
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Timon Ortloff
    Institute of Organic Chemistry, RWTH Aachen University
  • Koji Hirano
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Tetsuya Satoh
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Carsten Bolm
    Institute of Organic Chemistry, RWTH Aachen University
  • Masahiro Miura
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Oxidative alkenylation of N,N-disubstituted benzamides with alkenes accompanied by regioselective C–H bond cleavage proceeds efficiently in the presence of a Ru/Ag catalyst system together with a copper oxidant. The procedure is also applicable to phenylazoles.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 41 (2), 151-153, 2012-01-28

    Oxford University Press (OUP)

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