Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide‐Functionalized NHC Ligand

Shun Kawabata, Hiromu Tokura, Hiroyuki Chiyojima, Masaki Okamoto, Satoshi Sakaguchi

doi:10.1002/adsc.201100897

Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide‐Functionalized NHC Ligand

DOI Web Site Web Site 被引用文献6件参考文献53件

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<jats:title>Abstract</jats:title><jats:p>An enantioselective hydrosilylation of prochiral ketones was achieved by using a catalytic amount of the readily accessible and air‐ and moisture‐stable iridium complex [IrCl(cod)(NHC)] at room temperature.</jats:p>

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Advanced Synthesis & Catalysis

Advanced Synthesis & Catalysis 354 (5), 807-812, 2012-03-13

Wiley

Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide‐Functionalized NHC Ligand

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Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide‐Functionalized NHC Ligand

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