Substitution‐Pattern‐ and Counteranion‐Depending Ion‐Pairing Assemblies Based on Electron‐Deficient Porphyrin–Au<sup>III</sup> Complexes

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  • Hiroki Tanaka
    Department of Applied Chemistry College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
  • Yohei Haketa
    Department of Applied Chemistry College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
  • Nobuhiro Yasuda
    Research and Utilization Division Japan Synchrotron Radiation Research Institute Sayo 679-5198 Japan
  • Hiromitsu Maeda
    Department of Applied Chemistry College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan

書誌事項

公開日
2019-05-15
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/asia.201900422
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Porphyrin–Au<jats:sup>III</jats:sup> complexes, which were partially or totally modified with C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub> at the <jats:italic>meso</jats:italic> positions, were synthesized. The highly electron‐withdrawing substituents induced electron‐deficient states and Lewis acid properties. Single‐crystal X‐ray analysis of the ion pairs revealed ion‐pairing assemblies with characteristics dependent on the number and substitution pattern of the C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub> units and the geometries of the anions.</jats:p>

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