Peroxygenase reactions catalyzed by cytochromes P450
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説明
Cytochromes P450 (P450s) catalyze monooxygenation of a wide range of less reactive organic molecules under mild conditions. By contrast with the general reductive oxygen activation pathway of P450s, an H2O2-shunt pathway does not require any supply of electrons and protons for the generation of a highly reactive intermediate (compound I). Because the low cost of H2O2 allows us to use it in industrial-scale synthesis, the H2O2-shunt pathway is an attractive process for monooxygenation reactions. This review focuses on the P450-catalyzed monooxygenation of organic molecules using H2O2 as the oxidant.
収録刊行物
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- JBIC Journal of Biological Inorganic Chemistry
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JBIC Journal of Biological Inorganic Chemistry 19 (4-5), 529-539, 2014-02-06
Springer Science and Business Media LLC