Three-dimensional structures and lithium-ion conduction pathways of (Li2S) (GeS2)100− superionic glasses

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Abstract The conduction pathways of Li ions in (7Li2S)x(GeS2)100 − x glasses (x = 40, 50, and 60) were predicted and visualized by combining reverse Monte Carlo (RMC) modeling and the bond valence sum (BVS) approach, using synchrotron X-ray and time-of-flight neutron diffraction data. The conduction pathways of the Li ions could be classified into four grades, according to the magnitude of |ΔV(Li)|: (I) |ΔV(Li)|

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