Slow magnetic relaxation in a 4,2-ribbon like FeIII2CoII heterobimetallic chain
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説明
The reaction of Co(NO(3))(2)·6H(2)O and 3-benzoylpyridine with the low-spin iron(III) complex, H[Fe(III)(phen)(CN)(4)], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{Fe(III)(phen)(CN)(4)}(2)Co(II)(3-bpe)(2)] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.
収録刊行物
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- Dalton Transactions
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Dalton Transactions 41 (44), 13575-, 2012
Royal Society of Chemistry (RSC)
