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3- and 4-(α-diazobenzyl)pyridine-N-oxides as photoresponsive magnetic couplers for 2p–4f heterospin systems: formation of carbene–Tb<sup>III</sup> and carbene–Dy<sup>III</sup> single-molecule magnets
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- Kensuke Murashima
- Graduate School of Pharmaceutical Sciences
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- Satoru Karasawa
- Graduate School of Pharmaceutical Sciences
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- Kenji Yoza
- Bruker AXS K.K.
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- Yuji Inagaki
- Department of Applied Quantum Physics
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- Noboru Koga
- Graduate School of Pharmaceutical Sciences
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Description
<p>Dinuclear TbIII – and DyIII – <bold>D1pyO</bold> complexes were photolyzed to afford heterospin SMMs with <italic>U</italic>eff/<italic>k</italic>B = 30 and 39 K, respectively.</p>
Journal
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- Dalton Transactions
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Dalton Transactions 45 (16), 7067-7077, 2016
Royal Society of Chemistry (RSC)
