Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene–pyridine complex and <i>ortho</i>-functionalized pyridine derivatives
-
- Yuhei Katsuma
- Department of Applied Chemistry
-
- Hiroki Asakawa
- Department of Applied Chemistry
-
- Makoto Yamashita
- Department of Molecular and Macromolecular Chemistry
この論文をさがす
説明
<p>The reaction of pinB-BMes2 with Xyl-NC and pyridine results in the formation of a pyridine-coordinated boraalkene that exhibits an intense color. In the presence of an excess of pyridine, the <italic>ortho</italic> C–H bond of pyridine was selectively functionalized.</p>
収録刊行物
-
- Chemical Science
-
Chemical Science 9 (5), 1301-1310, 2018
Royal Society of Chemistry (RSC)
関連研究データ
もっと見る- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1360567183575648640
-
- ISSN
- 20416539
- 20416520
-
- 資料種別
- journal article
-
- データソース種別
-
- Crossref
- KAKEN
- OpenAIRE
