Phase transition in porous electrodes. III. For the case of a two component electrolyte

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  • Kenji Kiyohara
    National Institute of Advanced Industrial Science and Technology (AIST) 1 Health Research Institute, , Ikeda, Osaka 563-8577, Japan
  • Hiroshi Shioyama
    National Institute of Advanced Industrial Science and Technology (AIST) 2 Research Institute for Ubiquitous Energy Devices, , Ikeda, Osaka 563-8577, Japan
  • Takushi Sugino
    National Institute of Advanced Industrial Science and Technology (AIST) 1 Health Research Institute, , Ikeda, Osaka 563-8577, Japan
  • Kinji Asaka
    National Institute of Advanced Industrial Science and Technology (AIST) 1 Health Research Institute, , Ikeda, Osaka 563-8577, Japan
  • Yasushi Soneda
    National Institute of Advanced Industrial Science and Technology (AIST) 3 Energy Technology Research Institute, , Tsukuba, Ibaraki 305-8564, Japan
  • Kiyoaki Imoto
    National Institute of Advanced Industrial Science and Technology (AIST) 3 Energy Technology Research Institute, , Tsukuba, Ibaraki 305-8564, Japan
  • Masaya Kodama
    National Institute of Advanced Industrial Science and Technology (AIST) 3 Energy Technology Research Institute, , Tsukuba, Ibaraki 305-8564, Japan

抄録

<jats:p>The electrochemical thermodynamics of electrolytes in porous electrodes is qualitatively different from that in the bulk with planar electrodes when the pore size is comparable to the size of the electrolyte ions. In this paper, we discuss the thermodynamics of a two component electrolyte in a porous electrode by using Monte Carlo simulation. We show that electrolyte ions are selectively adsorbed in porous electrodes and the relative concentration of the two components significantly changes as a function of the applied voltage and the pore size. This selectivity is observed not only for the counterions but also for the coions.</jats:p>

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