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Anthenes: Model systems for understanding the edge state of graphene nanoribbons
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- Akihito Konishi
- 1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
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- Yasukazu Hirao
- 1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
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- Takashi Kubo
- 1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
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- Masayoshi Nakano
- 3Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan
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- Kenji Kamada
- 4Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST), AIST Kansai Center, Ikeda, Osaka 563-8577, Japan
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Description
<jats:title>Abstract</jats:title><jats:p>The edge state, which is a peculiar magnetic state in zigzag-edged graphene nanoribbons (ZGNRs) originating from an electron–electron correlation in an edge-localized π-state, has promising applications for magnetic and spintronics devices and has attracted much attention of physicists, chemists, and engineers. For deeper understanding of the edge state, precise fabrication of edge structures in ZGNRs has been highly demanded. We focus on anthenes, which are <jats:italic>peri</jats:italic>-condensed anthracenes that have zigzag and armchair edges on the molecular periphery, as model systems for understanding, and indeed prepare and characterize them. This paper summarizes our recent studies on the origin of the edge state by investigating anthenes in terms of the relationship between the molecular structure and spin-localizing character.</jats:p>
Journal
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- Pure and Applied Chemistry
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Pure and Applied Chemistry 86 (4), 497-505, 2014-04-17
Walter de Gruyter GmbH
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Details 詳細情報について
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- CRID
- 1360567187814334848
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- ISSN
- 13653075
- 00334545
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE