Selective Hydrogenation of C=C bond in Cinnamaldehyde on Pd Step Sites of Pd/Al2O3

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  • Kazumasa Murata
    Graduate School of Engineering, Nagoya University, Nagoya, Aichi 464-8603 , Japan
  • Takumi Shiotani
    Graduate School of Engineering, Nagoya University, Nagoya, Aichi 464-8603 , Japan
  • Junya Ohyama
    Faculty of Advanced Science and Technology, Kumamoto University, Kumamoto 860-8555 , Japan
  • Atsushi Satsuma
    Graduate School of Engineering, Nagoya University, Nagoya, Aichi 464-8603 , Japan

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<jats:title>Abstract</jats:title> <jats:p>We found a positive correlation between C=C selective hydrogenation activity of cinnamaldehyde (CAL) and the fraction of the Pd step site on Pd nanoparticles. Owing to a high fraction of step sites, Pd/θ-Al2O3 catalysts with Pd particle size of 5–10 nm were highly active for the C=C selective hydrogenation of CAL.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 50 (4), 599-602, 2020-12-26

    Oxford University Press (OUP)

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