Shape-selective zeolite catalysis for bioplastics production

  • Michiel Dusselier
    Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.
  • Pieter Van Wouwe
    Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.
  • Annelies Dewaele
    Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.
  • Pierre A. Jacobs
    Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.
  • Bert F. Sels
    Center for Surface Chemistry and Catalysis, KU Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.

書誌事項

公開日
2015-07-03
権利情報
  • http://www.sciencemag.org/about/science-licenses-journal-article-reuse
DOI
  • 10.1126/science.aaa7169
公開者
American Association for the Advancement of Science (AAAS)

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説明

<jats:title>Synthesizing more sustainable plastics</jats:title> <jats:p> Zeolites can help synthesize cheaper plastic precursors from biologically sourced feedstocks. Producing sustainable plastics must compete with more cost-effective petrochemical-based synthesis routes. Dusselier <jats:italic>et al.</jats:italic> developed a zeolite-based strategy to catalyze the transformation of microbially produced lactic acid into lactide, a difficult-to-synthesize precursor of biodegradable polylactic acid plastics. The selectivity of nearly 80% is based on active site spatial confinement in the zeolite micropores. This step substantially simplifies current high-cost synthesis routes and generates nearly zero waste using current reactor technologies. </jats:p> <jats:p> <jats:italic>Science</jats:italic> , this issue p. <jats:related-article xmlns:xlink="http://www.w3.org/1999/xlink" ext-link-type="doi" issue="6243" page="78" related-article-type="in-this-issue" vol="349" xlink:href="10.1126/science.aaa7169">78</jats:related-article> </jats:p>

収録刊行物

  • Science

    Science 349 (6243), 78-80, 2015-07-03

    American Association for the Advancement of Science (AAAS)

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