Laboratory studies of negative ion reactions with atmospheric trace constituents

  • F. C. Fehsenfeld
    Aeronomy Laboratory, NOAA Environmental Research Laboratories, Boulder, Colorado 80302
  • E. E. Ferguson
    Aeronomy Laboratory, NOAA Environmental Research Laboratories, Boulder, Colorado 80302

書誌事項

公開日
1974-10-15
DOI
  • 10.1063/1.1682474
公開者
AIP Publishing

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説明

<jats:p>A flowing afterglow system has been used to measure 296°K reaction rate constants and equilibrium constants for a number of negative ion reactions with atmospheric constituents. Three-body association reactions of O−, OH−, O2−, O3−, Cl−, CO3−, OH−(H2O), and O2−(H2O) with H2O have been measured and association rate constants for several ions with CO2 and SO2 have been measured. A number of binary reactions for these ions and their hydrates have been measured with H2O, CO2, SO2, NO2, O3, and NO. Some equilibrium constants for negative ion hydration and some equilibrium constants for solvent (H2O, CO2, and SO2) exchange to several negative ions are reported.</jats:p>

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