Zn−Zn Porphyrin Dimer-Sensitized Solar Cells: Toward 3-D Light Harvesting
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- Attila J. Mozer
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Matthew J. Griffith
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- George Tsekouras
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Pawel Wagner
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Gordon G. Wallace
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Shogo Mori
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Kenji Sunahara
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Masanori Miyashita
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- John C. Earles
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Keith C. Gordon
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Luchao Du
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Ryuzi Katoh
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- Akihiro Furube
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
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- David L. Officer
- Intelligent Polymer Research Institute, ARC Centre for Excellence for Electromaterials Science, University of Wollongong, Wollongong 2522, Australia, Department of Fine Materials Engineering, Shinshu University, Nagano, 386-8567, Japan, MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Otago, Dunedin, New Zealand, and National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Japan
説明
Zn-Zn porphyrin dimers have been incorporated into thin dye-sensitized solar cells (DSSCs) to boost their light harvesting efficiency. The photoexcited dimers show efficient and fast electron injection into TiO(2) indicating that both photoexcited chromophores contribute to current generation. The improved light harvesting ability coupled to enhanced DSSC performance demonstrates the potential of 3-D light harvesting arrays as next generation light harvesters for artificial solar energy conversion systems.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 131 (43), 15621-15623, 2009-10-09
American Chemical Society (ACS)
