Interactions of Hydrogen with Pd@MOF Composites

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  • Abdelmalek Malouche
    Institut de Chimie et des Matériaux Paris-Est (UMR 7182) Université Paris Est CNRS UPEC 2–8 Rue Henri Dunant F-94320 Thiais France
  • Claudia Zlotea
    Institut de Chimie et des Matériaux Paris-Est (UMR 7182) Université Paris Est CNRS UPEC 2–8 Rue Henri Dunant F-94320 Thiais France
  • Petra Ágota Szilágyi
    School of Engineering and Materials Science Queen Mary University of London Mile End Road E1 4NS London United Kingdom

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Description

<jats:title>Abstract</jats:title><jats:p>Physisorption and chemisorption of hydrogen on solid‐state materials are two fundamentally different interactions, both of which display advantages and drawbacks for hydrogen storage. It has been hypothesised that their combination by merging two classes of materials showing different sorption behaviour towards hydrogen in the same composite may synergistically combine their desirable properties. As representatives of such composites, palladium nanoparticles, nanoclusters, and single atoms have been encapsulated in a metal‐organic framework matrix, embedded, or immobilised in its pores, respectively. In this minireview, we review advances on the understanding and potential applications of the combination of Pd with metal‐organic framework matrices through the analysis of the nanocomposite materials’ interaction with hydrogen and sorption properties.</jats:p>

Journal

  • ChemPhysChem

    ChemPhysChem 20 (10), 1282-1295, 2019-02-06

    Wiley

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