Mechanistic insights into intramolecular ortho-amination/hydroxylation by nonheme Fe<sup>IV</sup>NTs/Fe<sup>IV</sup>O species: the σ vs. the π channels

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<p>Intra molecular aromatic amination/hydroxylation by iron(<sc>iv</sc>)-species (imido and oxo). The following aspects are discussed in this study: (a) reasons for high reactivity; (b) comparative oxidative abilities; (c) prediction of σ and π pathways.</p>

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