Construction of biporous coordination networks via π–π interaction

DOI Web Site 研究データあり 被引用文献2件

説明

Biporous 3D-coordination networks {[(ZnI2)3(1)2(G)]·solvents}z (G = triphenylene or perylene) were synthesized by the electron-deficient triazine ligand (1) with ZnI2 in the presence of an electron-rich guest (G) via charge-transfer interaction. The frameworks of networks include predictable infinite aromatic stacking between 1 and G. Also, single-crystal-to-single-crystal guest-exchange was successfully performed in the channels without loss of intercalated guest molecules.

収録刊行物

  • CrystEngComm

    CrystEngComm 2005

    Royal Society of Chemistry (RSC)

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