Local orientation of chains at crystal/amorphous interfaces buried in isotactic polypropylene thin films

  • Daisuke Kawaguchi
    Department of Applied Chemistry, Kyushu University, Fukuoka 819-0395, Japan
  • Kentaro Yamamoto
    Department of Applied Chemistry, Kyushu University, Fukuoka 819-0395, Japan
  • Tatsuki Abe
    Department of Applied Chemistry, Kyushu University, Fukuoka 819-0395, Japan
  • Naisheng Jiang
    Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11794-2275, USA
  • Tadanori Koga
    Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, New York 11794-2275, USA
  • Satoru Yamamoto
    Center for Polymer Interface and Molecular Adhesion Science, Kyushu University, Fukuoka 819-0395, Japan
  • Keiji Tanaka
    Department of Applied Chemistry, Kyushu University, Fukuoka 819-0395, Japan

Description

<jats:p>The preferential orientation of the crystalline lamellae for isotactic polypropylene in spin-coated films was examined by grazing incidence of wide-angle X-ray diffraction in conjunction with sum frequency generation vibrational spectroscopy.</jats:p>

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